| # | Title | Rating | Length |
|---|
| 1 | “Live at Pompeii” Radio Advert #1 | | 0:19 |
| 2 | “Live at Pompeii” Radio Advert #2 | | 0:59 |
| 3 | “Live at Pompeii” Radio Advert #3 | | 0:57 |
| 4 | “Live at Pompeii” Radio Advert #4 | | 0:57 |
| 5 | “Live at Pompeii” Radio Advert #5 | | 0:33 |
| 6 | “Live at Pompeii” Radio Advert #6 | | 0:59 |
| 7 | “Live at Pompeii” Radio Advert #7 | | 0:29 |
| 8 | Careful With That Axe Eugene (ballet version) | | 3:27 |
| 9 | La Vallée: Free Four (film version)- recorded at:
- Château d'Hérouville in Hérouville, Val-d'Oise, Île-de-France, France (in 1972)
- recording of:
- Free Four
- lyricist and composer:
- Roger Waters
- publisher:
- Artemis Muziekuitgeverij B V, Hampshire House Publishing Corp., Pink Floyd Music Publishers Ltd., Roger Waters Music Overseas Ltd., TRO-Hampshire House Publishing Corp., Warner–Tamerlane Publishing Corp. , Warner/Chappell Music Publishing Ltd. , World Copyrights and World Copyrights Ltd.
| | 2:08 |
| 10 | La Vallée: Instrumental | | 1:38 |
| 11 | La Vallée: Obscured by Clouds- recorded at:
- Château d'Hérouville in Hérouville, Val-d'Oise, Île-de-France, France (in 1972)
- recording of:
- Obscured by Clouds
- composer:
- David Gilmour and Roger Waters
- publisher:
- Artemis Muziekuitgeverij B V, Hampshire House Publishing Corp., Pink Floyd Music Publishers Ltd., Roger Waters Music Overseas Ltd., TRO-Hampshire House Publishing Corp., Warner–Tamerlane Publishing Corp. , Warner/Chappell Music Publishing Ltd. , World Copyrights and World Copyrights Ltd.
| | 1:01 |
| 12 | La Vallée: Free Four (short version)- producer:
- Pink Floyd
- phonographic copyright (℗) by:
- The Gramophone Co., Ltd. (in 1972)
- recorded at:
- Château d'Hérouville in Hérouville, Val-d'Oise, Île-de-France, France (in 1972)
- edit of:
- Free Four by Pink Floyd
- recording of:
- Free Four (in 1972)
- lyricist and composer:
- Roger Waters
- publisher:
- Artemis Muziekuitgeverij B V, Hampshire House Publishing Corp., Pink Floyd Music Publishers Ltd., Roger Waters Music Overseas Ltd., TRO-Hampshire House Publishing Corp., Warner–Tamerlane Publishing Corp. , Warner/Chappell Music Publishing Ltd. , World Copyrights and World Copyrights Ltd.
| | 3:30 |
| 13 | Atom Heart Mother (1972‐05‐22)- recorded at:
- Olympisch Stadion in Amsterdam, Noord-Holland , Netherlands, Kingdom of the Netherlands (on 1972-05-22)
- live recording of:
- Atom Heart Mother (on 1972-05-22)
- orchestrator:
- Ron Geesin
- composer:
- Ron Geesin, David Gilmour , Nick Mason , Roger Waters and Richard Wright
- publisher:
- Artemis Muziekuitgeverij B V, Essex Music, Inc., Lupus Music Co. Ltd, Pink Floyd Music Publishers Ltd., Roger Waters Music Overseas Ltd., TRO-Hampshire House Publishing Corp., Warner/Chappell Music Publishing Ltd. , Westminster Music Ltd. and World Copyrights
| | 14:46 |
| 14 | Careful With That Axe, Eugene (1972‐05‐22) | | 11:24 |
| 15 | A Saucerful of Secrets (1972‐05‐22) | | 9:34 |
| 16 | “Live at Pompeii” Goofy Ad #1 | | 1:01 |
| 17 | “Live at Pompeii” Goofy Ad #2 | | 1:01 |
| 18 | “Live at Pompeii” Goofy Ad #3 | | 1:07 |
| 19 | “Live at Pompeii” Goofy Ad #4 | | 1:00 |
| 20 | Careful With That Axe, Eugene (1972‐06‐29) | | 7:42 |
| 21 | Set the Controls for the Heart of the Sun (1972‐06‐29)- recorded at:
- Brighton Dome in Brighton, Brighton and Hove, England, United Kingdom (on 1972-06-29)
- live recording of:
- Set the Controls for the Heart of the Sun (on 1972-06-29)
- lyricist and composer:
- Roger Waters
- publisher:
- Essex , Essex International, Essex Music International, Essex Music International, Inc., Lupus Music Co. Ltd, Magdalene Music, TRO-Essex Music International, Inc., TRO-Hampshire House Publishing Corp. and Westminster Music Ltd.
| | 9:06 |